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erma4kov [3.2K]

2 years ago

8

Strengths as bases:H2O, F-, Cl-, NO,, and CN-

1 answer:

navik [9.2K]2 years ago

3 0

Answer:

Cl^-<NO3^-<H2O<F^-<CN^-

Explanation:

When we talk about base strength we are referring to how easily a chemical specie accepts protons.

The greater the ability of a specie to accept H^+, the greater its base strength.

The order of increasing base strengths of the species listed are shown in the answer above.

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The given cell reactions is:

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Oxidation half reaction (anode): $Zn\rightarrow Zn^{2+}+2e^-$

Reduction half reaction (cathode): $Pb^{2+}+2e^-\rightarrow Pb$

First we have to calculate the cell potential for this reaction.

Using Nernest equation :

$E_{cell}=E^o_{cell}-\frac{2.303RT}{nF}\log \frac{[Zn^{2+}]}{[Pb^{2+}]}$

where,

F = Faraday constant = 96500 C

R = gas constant = 8.314 J/mol.K

T = room temperature = $25^oC=273+25=298K$

n = number of electrons in oxidation-reduction reaction = 2

$E^o_{cell}$ = standard electrode potential of the cell = +0.63 V

$E_{cell}$ = cell potential for the reaction = ?

$[Zn^{2+}]$ = 3.5 M

$[Pb^{2+}]$ = $2.0\times 10^{-4}M$

Now put all the given values in the above equation, we get:

$E_{cell}=(+0.63)-\frac{2.303\times (8.314)\times (298)}{2\times 96500}\log \frac{3.5}{2.0\times 10^{-4}}$

$E_{cell}=0.50V$

Therefore, the cell potential for this reaction is 0.50 V

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2 years ago