Answer:
is an aqueous reactant
is a liquid product
is a gaseous product
Explanation:
⇔ 
Hydrogen carbonate dissocates to form carbon dioxide and water. The acid (hydrogen carbonate) is in aqueous form and it dissociates to water (liquid) and carbon dioxide (a gas). It is also seen that the hydrogen carbonate is on the reactant side and it dissociates to produce water and carbon dioxide.
W<u> is an aqueous reactant</u> (a reactant undergoes changes in a chemical reaction
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<u> is a liquid product</u> (product refers to the species produced from chemical reaction)
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<u> is a gaseous product</u>
A) when the balanced equation of the reaction is:
H2CO3(aq) → HCO3 -(aq) + (H+)
and when we have Ka = 4.3 x10^-7 & PH = 7.4
So first we will get PKa = -㏒ Ka
PKa = -㏒(4.3x10^-7) = 6.37 by substitution with Pka value in the following formula:
PH = Pka + ㏒[salt/acid]
PH= PKa + ㏒[HCO3-]/[H2CO3]
㏒[HCO3-]/[H2CO3] = PH-Pka
[HCO3-] /[H2CO3] = 10^(7.4 - 6.37)
∴[HCO3-]/[H2CO3] = 11.7
∴[H2CO3]/[HCO3-] = 1/11.7 = 0.09
B) when The balanced equation for this reaction is:
H2PO42-(aq) → HPO4-(aq) + H+
and when we have Ka = 6.2x10^-8 & PH = 7.15
So Pka= -㏒Ka = -㏒(6.2x10^-8) = 7.2 by substitution by Pka value in the following formula:
PH = Pka + ㏒[salt/acid]
7.15= 7.2 + ㏒[HPO4]/[H2PO4]
-0.05 = ㏒[HPO4]/[H2PO4]
∴[HPO4]/[H2PO4] = 10^-0.05 = 0.89
∴[H2PO4]/[HPO4] = 1/0.89 = 1.12
c) H3PO4(aq) ↔ H2PO-(aq) + H+
the answer is: because we have Ka =7.5x10^-3 and it is a high value of Ka to make a good buffer, also we need a week acid with th salt of the week acid as H3PO4 is a strong acid so it does'nt make a goof buffer.
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