O2 gas is to effuse through a porous barrier in time t₁ = 4.98 minutes.
Under the same conditions;
the same number of moles of an unknown gas requires time t₂ = 6.34 minutes to effuse through the same barrier.
From Graham's Law of Diffusion;
Graham's Law of Diffusion states that, at a constant temperature and pressure; the rate of diffusion of a gas is inversely proportional to the square root of its density.
i.e
where K = constant
If we compare the rate o diffusion of two gases;
Since the density of a gas d is proportional to its relative molecular mass M. Then;
Rate is the reciprocal of time ; i.e
Thus; replacing the value of R into the above previous equation;we have:
Reason: 1) The graph of enthalpy Vs reaction coordinate suggest the reaction is endothermic in nature. For endothermic reaction, energy if product is more than that of reactant. Hence, option 1 i.e. </span><span>X = -ΔH cannot be correct. 2) Since the reaction is endothermic in nature, </span>energy if product is more than that of reactant. Hence, option 2 i.e. X = ΔH is correct. 3) Activation energy is energy difference between Reactant (A) and transition state (B). However, as per option C, activation energy (A.E.) is energy difference between product (C) and transition state (B), which is incorrect.