Additional information
Relative atomic mass(Ar) : A=7, G=16
The empirical formula : A₂G
<h3>Further explanation</h3>
Given
3.5g of element A
4.0g of element G
Required
the empirical formula for this compound
Solution
The empirical formula is the smallest comparison of atoms of compound forming elements.
The empirical formula also shows the simplest mole ratio of the constituent elements of the compound
mol of element A :
mol of element G :
mol ratio A : G = 0.5 : 0.25 = 2 : 1
1) is sulfuric acid
2)is nitrous acid
3)is hydrochlorous acid
4)is hydrobromous acid
5)is hydrophosphoric acid
6)is fluoric acid
7)is sulfuric acid
8)is chlorous acid
9)is nitric acid
10)is iodic acid
11)is acetous acid
12)is chlorous acid.
ΔHrxn = ΣδΗ(bond breaking) - ΣδΗ(bond making)
Bond enthalpies,
N ≡ N ⇒ 945 kJ mol⁻¹
N - Cl ⇒ 192 kJ mol⁻¹
Cl - Cl⇒ 242 kJ mol⁻¹
According to the balanced equation,
ΣδΗ(bond breaking) = N ≡ N x 1 + Cl - Cl x 3
= 945 + 3(242)
= 1671 kJ mol⁻¹
ΣδΗ(bond making) = N - Cl x 3 x 2
= 192 x 6
= 1152 kJ mol⁻¹
δHrxn = ΣδΗ(bond breaking) - ΣδΗ(bond making)
= 1671 kJ mol⁻¹ - 1152 kJ mol⁻¹
= 519 kJ mol⁻¹
Given that
Mass of water = 65.34 g
Amount of heat = mass of water * specific heat (temperature change
)
= 65.34 g * 4.184 J / g-C ( 21.75-18.43 )C
= 907.63 J
= 0.908 KJ
And
1 cal = 4.186798 J
907.63 J * 1 cal / 4.186798 J =216.78 cal
Or0.218 kcal
