1. to calculate molar mass , you need average atomic mass of each element.
formula is simple
suppose we have Na2CO3
here it says
there are
2 atoms of Na
1 atom of C
3 atom of O
now
molar mass = (total atoms of Na × average atomic mass of Na) + ( total atom of C × average atomic mass of C )+ (total atom of O × average atomic mass of O)
i hope you can figure out it now.
in case of (NH4)2
this means you have 2 count of NH4
so total atoms of N = 2
total atoms of H = 4×2 = 8
so on you can now figure it out
2. balanced equation
here LHS and RHS shoild have same number of atoms of each element .
for example
H2 + Cl2 => 2HCl
here 2 atoms of H combined with 2 atoms of Cl , we know H and Cl combined and formed HCl now because total H atoms are 2 and Cl atoms are 2 in LHS then we should also have 2 atoms of each in right side
so thats why we have 2HCl in right side.
Try to figure out . let me know if need any help