B boiling point https://chem.libretexts.org/Bookshelves/Introductory_Chemistry/Map%3A_Introductory_Chemistry_(Tro)/03%3A_Matter_and_Energy/3.05%3A_Differences_in_Matter%3A_Physical_and_Chemical_Properties#Summary
Answer:
a) C6H5COOH + H2O ↔ H3O+ + C6H5COO-
b) [ H3O+ ] = 2.517 E-3 M
c) pH = 2.599
Explanation:
a) balanced equation:
C6H5COOH + H2O ↔ H3O+ + C6H5COO-
⇒ Ka = ( [ H3O+ ] * [ C6H5COO- ] ) / [ C6H5COOH ] = 6.5 E-5
mass balance:
0.10 m = [ C6H5COO- ] + [ C6H5COOH ].....(1)
charge balance:
[ H3O+ ] = [ C6H5COO- ] + [ OH- ] .......[ OH- ] : comes from water, it's not significant
⇒ [ H3O+ ] = [ C6H5COO- ] .........(2)
b) (2) in (1):
⇒ 0.10 M = [ H3O+ ] + [ C6H5COOH ]
⇒ [ C6H5COOH ] = 0.10 - [ H3O+ ]
⇒ Ka = [ H3O+ ]² / ( 0.1 - [ H3O+ ] ) = 6.5 E-5
⇒ [ H3O+ ]² + 6.5 E-5 [ H3O+ ] - 6.5 E-6 = 0
⇒ [ H3O+ ] = 2.517 E-3 M
c) pH = - log [ H3O+ ]
⇒ pH = - Log ( 2.517 E-3 )
⇒ pH = 2.599
Answer: A and D, I believe
Explanation:
0.003 moles of NaOH was used in the titration.
<h3>What is titration?</h3>
The concentration of an identified analyte can be found using a simple laboratory technique called titration. As a standard solution with a given concentration and volume, a reagent known as the titrant or titrator is created.
By using a solution with a known concentration to measure the concentration of an unknown solution, this process is known as titration. To a known volume of the analyte (the unknown solution), the titrant (the known solution) is typically added from a buret until the reaction is finished. To ascertain the unknown concentration of an identifiable analyte, titration, commonly referred to as titrimetry, is a widely used quantitative laboratory analytical technique (Medwick and Kirschner, 2010). Volume measurements are a crucial component of titration
Concentration in mol/dm3 =
Amount of solution mol
= concentration in mol/dm3 × volume in dm3
Amount of sodium hydroxide
= 0.100 × 0.0250
= 0.00250 mol
To know more about titration, visit:
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Answer:
a) equilibrium shifts towards the right
b) equilibrium shifts towards the right
c) equilibrium shifts towards the left
d) has no effect on equilibrium position
e) has no effect on equilibrium position
Explanation:
A reversible reaction may attain equilibrium in a closed system. A chemical system is said to be in a state of dynamic equilibrium when the rate of forward reaction is equal to the rate of reaction.
According to Le Chateliers principle, when a constraint such as a change in temperature, pressure, volume or concentration is imposed upon a system in equilibrium, the equilibrium position shifts in such a way as to annul the constraint.
When the concentration of reactants is increased, the equilibrium position is shifted towards the right hand side and more products are formed. For an endothermic reaction, the reverse reaction is favoured by a decrease in temperature. Increase in pressure has no effect on the system since there are equal volumes on both sides of the reaction equation. Similarly, the addition of a catalyst has no effect on the equilibrium position since it speeds up both the forward and reverse reactions to the same extent.
