Which of the following equalities is not correct?
2 answers:
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Answer:
The concentration of cyclopropane after 22.0 hour is 0.0457 M.
Explanation:
Conversion of cyclopropane into propene follows first order kinetics.
The integrated rate of first order kinetic is given by :
= Initial concentration of reactant
= final concentration of reactant after time t
k = rate constant of the reaction
We have :
Rate constant of the reaction = k =
t = 22.0 hour
[A] =?
The concentration of cyclopropane after 22.0 hour is 0.0457 M.
Explanation:
It is known that molarity is the number of moles present in a liter of solution.
Mathematically, Molarity =
Hence, calculate the molarity of given solution as follows.
Molarity of citric acid =
=
= 0.173 M
As citric acid is a triprotic acid so, upon dissociation it gives three hydrogen ions.
Normality = Molarity × no. of hydrogen or hydroxide ions
= 0.173 × 3
= 0.519 N
Thus, we can conclude that molarity of given solution is 0.173 and its normality is 0.519 N.
Answer: The reaction order with respect to A is m
Explanation:
Order of the reaction is defined as the sum of the concentration of terms on which the rate of the reaction actually depends. It is the sum of the exponents of the molar concentration in the rate law expression.
Elementary reactions are defined as the reactions for which the order of the reaction is same as its molecularity and order with respect to each reactant is equal to its stoichiometric coefficient as represented in the balanced chemical reaction.
For the given reaction:
In this equation, the order with respect to each reactant is not equal to its stoichiometric coefficient which is represented in the balanced chemical reaction.
Hence, this is not considered as an elementary reaction.
Order with respect to A = m
Order with respect to B = n
Overall order = m+n
Thus order with respect to A is m.