A scientific law is a statement that is universally accepted and answers the "how?" question.
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Answer:
Detail is given below
Explanation:
Atomic radii trend along group:
As we move down the group atomic radii increased with increase of atomic number. The addition of electron in next level cause the atomic radii to increased. The hold of nucleus on valance shell become weaker because of shielding of electrons thus size of atom increased.
As the size of atom increases the ionization energy from top to bottom also decreases because it becomes easier to remove the electron because of less nuclear attraction and as more electrons are added the outer electrons becomes more shielded and away from nucleus.
In A we can see that there is one positive charge and force of attraction is 2.30×10⁻⁸ N and distance is 0.10 nm
In B we can see that negative charge is further away from nucleus because of greater distance thus force of attraction will be less. 0.58×10⁻⁸ N
In C this distance further increases and force also goes in decreasing 0.26×10⁻⁸ N.
Answer: There are now 2.07 moles of gas in the flask.
Explanation:
P= Pressure of the gas = 697 mmHg = 0.92 atm (760 mmHg= 1 atm)
V= Volume of gas = volume of container = ?
n = number of moles = 1.9
T = Temperature of the gas = 21°C=(21+273)K= 294 K (0°C = 273 K)
R= Value of gas constant = 0.0821 Latm\K mol
When more gas is added to the flask. The new pressure is 775 mm Hg and the temperature is now 26 °C, but the volume remains same.Thus again using ideal gas equation to find number of moles.
P= Pressure of the gas = 775 mmHg = 1.02 atm (760 mmHg= 1 atm)
V= Volume of gas = volume of container = 49.8 L
n = number of moles = ?
T = Temperature of the gas = 26°C=(26+273)K= 299 K (0°C = 273 K)
R= Value of gas constant = 0.0821 Latm\K mol
Thus the now the container contains 2.07 moles.
(a) One form of the Clausius-Clapeyron equation is
ln(P₂/P₁) = (ΔHv/R) * (1/T₁ - 1/T₂); where in this case:
Solving for ΔHv:
- ΔHv = R * ln(P₂/P₁) / (1/T₁ - 1/T₂)
- ΔHv = 8.31 J/molK * ln(5.3/1.3) / (1/358.96 - 1/392.46)
(b) <em>Normal boiling point means</em> that P = 1 atm = 101.325 kPa. We use the same formula, using the same values for P₁ and T₁, and replacing P₂ with atmosferic pressure, <u>solving for T₂</u>:
- ln(P₂/P₁) = (ΔHv/R) * (1/T₁ - 1/T₂)
- 1/T₂ = 1/T₁ - [ ln(P₂/P₁) / (ΔHv/R) ]
- 1/T₂ = 1/358.96 K - [ ln(101.325/1.3) / (49111.12/8.31) ]
(c)<em> The enthalpy of vaporization</em> was calculated in part (a), and it does not vary depending on temperature, meaning <u>that at the boiling point the enthalpy of vaporization ΔHv is still 49111.12 J/molK</u>.
Answer:
H₂: 0.48, N₂: 0.43; Ar: 0.09
Explanation:
First of all, sum all the pressures to know the total pressure in the mixture.
434 Torr + 389.9 Torr + 77.9 Torr = 901.8 Torr
Mole fraction = Pressure gas / Total Pressure
Mole Fraction H₂: 434 Torr /901.8 Torr = 0.48
Mole Fraction N₂: 389.9 /901.8 Torr =0.43
Mole Fraction Ar: 77.9 /901.8 Torr = 0.09
Remember: <u>SUM OF MOLE FRACTION = 1</u>