A substance melting is a physical change and the properties of the substance will remain same, only that the substance will just become liquid.
On the other hand, burning is a chemical change which produces an entirely new compount(in most cases, ash) which does not have the same properties as the original object
Localized molecular orbitals are molecular orbitals which are concentrated in a limited spatial region of a molecule, for example a specific bond or a lone lake on a specific atom.