For 1. 00 l of an aqueous buffer containing 60. 0 mmol of acetic acid (pa=4. 76) and 40. 0 mmol of acetate, the pH of this buffer is 4.58.
<h3>What is handerson Hasselbalch equation? </h3>
It is expressed as:
pH = pKa + log [A-]/[HA]
where,
[A-] is the molar concentration of conjugate base
[HA] is the molar concentration of weak acid
Given,
pKa = 4.76
<h3>Calculation of concentration:</h3>
C = n/V
= 60/1000
= 0.06M
C = 40/1000
= 0.04M
Now, substituting values in equation we get,
pH = 4.76 + log(0.04/0.06)
pH = 4.76 + (-0.176)
pH = 4.58
Thus by using Henderson Hasselbalch equation we find the value of pH of the buffer is 4.58.
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