Answer:
7.00
Explanation:
When the solutions are mixed, the HCl dissociates to form the ions H+ and Cl-. The ion H+ will react with the NH3 to form NH4+. The stoichiometry for this is 1 mol of HCl to 1 mol of H+ to 1 mol of Cl-, and 1 mol of H+ to 1 mol of NH3 to 1 mol of NH4+.
First, let's find the number of moles of each one of them, multiplying the concentration by the volume:
nH+ = 0.15 M * 25 mL = 3.75 mmol
nNH3 = 0.52 M * 25 mL = 13 mmol
So, all the H+ is consumed, and the neutralization is completed, thus pH will be the pH of the solvent (water), pH = 7.00.
Answer: 0.028 grams
Explanation:
Depression in freezing point :
Formula used for lowering in freezing point is,
or,
where,
= change in freezing point
= freezing point constant (for benzene} =
m = molality
Putting in the values we get:
0.028 grams of DDT (solute) must be dissolved in 209.0 grams of benzene to reduce the freezing point by 0.400°C.
Answer:
All of the above.
Explanation:
In positive deviation from Raoult's Law occur when the vapour pressure of components is greater than what is expected value in Raoult's law.
When a solution is non ideal then it shows positive or negative deviation.
Let two solutions A and B to form non- ideal solutions.let the vapour pressure of component A is and vapour pressure of component B is .
= Vapour pressure of component A in pure form
= Vapour pressure of component B in pure form
=Mole fraction of component A
=Mole fraction of component B
The interaction between A- B is less than the interaction A- A and B-B interaction.Therefore, the escaping tendency of liquid molecules in mixture is greater than the escaping tendency in pure form.Hence, the vapour pressure of a mixture is greater than the initial value of vapour pressure.
,
Therefore,
Therefore, the enthalpy of mixing is greater than zero and change in volume is greater than zero.
Hence, option a,b,c and d are true.