A crystal structure is an ordered arrangement of atoms,ions or molecules in a regular repeating pattern,it is a form of solid state of matter and differs from liquid and gaseous states of matte in which the atoms or molecules are random or haphazard.
The answer is (3) Cu2O. Copper (I) has an oxidation state of +1 (that's what the "I" indicates). You can also think of this as copper (I) having a charge of +1. Oxygen has an oxidation state of -2 (that's just a rule you have to know), and you can think of it as oxygen having a charge of -2. You need oxidation numbers in a neutral compound to add up to 0 (or charges in a neutral compond to add up to 0), so you need two Cu to balance the O, which is Cu2O.