Answer:
Only changes in temperature will influence the equilibrium constant 
. The system will shift in response to certain external shocks. At the new equilibrium 
will still be equal to , but the final concentrations will be different.
The question is asking for sources of the shocks that will influence the value of . For most reversible reactions:
- External changes in the relative concentration of the products and reactants.
For some reversible reactions that involve gases:
- Changes in pressure due to volume changes.
Catalysts do not influence the value of . See explanation.
Explanation:
.
Similar to the rate constant, the equilibrium constant depends only on:
the standard Gibbs energy change of the reaction, and
the absolute temperature (in degrees Kelvins.)
The reversible reaction is in a dynamic equilibrium when the rate of the forward reaction is equal to the rate of the backward reaction. Reactants are constantly converted to products; products are constantly converted back to reactants. However, at equilibrium 
the two processes balance each other. The concentration of each species will stay the same.
Factors that alter the rate of one reaction more than the other will disrupt the equilibrium. These factors shall change the rate of successful collisions and hence the reaction rate.
- Changes in concentration influence the number of particles per unit space.
- Changes in temperature influence both the rate of collision and the percentage of particles with sufficient energy of reaction.
For reactions that involve gases,
- Changing the volume of the container will change the concentration of gases and change the reaction rate.
However, there are cases where the number of gases particles on the reactant side and the product side are equal. Rates of the forward and backward reaction will change by the same extent. In such cases, there will not be a change in the final concentrations. Similarly, catalysts change the two rates by the same extent and will not change the final concentrations. Adding noble gases will also change the pressure. However, concentrations stay the same and the equilibrium position will not change.
Answer:
I would expect to extract the acetic acid.
Explanation:
In the first step, since we are adding a concentrated acid,<u> it will react with the bases present in the mixture (diethylamine and ammonia) </u><u>forming salts</u><u>, </u><u>which are soluble in water</u>. Therefore, after draining the aqueous layer, we will have phenol and acetic acid left in the organic layer.
In the second step, we are adding a diluted base, so it will react with a strong acid. This compound is acetic acid, and its salt will be present in the aqueous layer. Phenol will be left on the organic layer.
Answer:
6.23 KOH 90% son necesarios
Explanation:
Una solución 1N de KOH requiere 1equivalente (En KOH, 1eq = 1mol) por cada litro de solución.
Para responder esta pregunta se requiere hallar los equivalentes = Moles de KOH para preparar 100mL = 0.100L de una solución 1N. Haciendo uso de la masa molar de KOH y del porcentaje de pureza del KOH se pueden calcular los gramos requeridos para preparar la solución así:
<em>Equivalentes KOH:</em>
0.100L * (1eq / L) = 0.100eq = 0.100moles
<em>Gramos KOH -Masa molar: 56.1056g/mol-:</em>
0.100moles * (56.1056g/mol) = 5.61 KOH se requieren
<em>KOH 90%:</em>
5.61g KOH * (100g KOH 90% / 90g KOH) =
<h3>6.23 KOH 90% son necesarios</h3>
Answer:
1.7 bar
Explanation:
We can use the <em>Ideal Gas Law</em> to calculate the individual gas pressure.
pV = nRT Divide both sides by V
p = (nRT)/V
Data: n = 1.7 × 10⁶ mol
R = 0.083 14 bar·L·K⁻¹mol⁻¹
T = 22 °C
V = 2.5 × 10⁷ L
Calculations:
(a) <em>Change the temperature to kelvins
</em>
T = (22 + 273.15) K
= 295.15 K
(b) Calculate the pressure
p = (1.7 × 10⁶ × 0.083 14 × 295.15)/(2.5× 10⁷)
= 1.7 bar
<span>In a solution of water and ethanol, hydrogen bonding is the strongest intermolecular force between molecules. Hydrogen bonding occurs when the partially negative oxygen end of one of the molecules is attracted to the partially positive hydrogenend of another molecule.</span>
