Answers and Explanation:
a)- The chemical equation for the corresponden equilibrium of Ka1 is:
2. HNO2(aq)⇌H+(aq)+NO−2
Because Ka1 correspond to a dissociation equilibrium. Nitrous acid (HNO₂) losses a proton (H⁺) and gives the monovalent anion NO₂⁻.
b)- The relation between Ka and the free energy change (ΔG) is given by the following equation:
ΔG= ΔGº + RT ln Q
Where T is the temperature (T= 25ºc= 298 K) and R is the gases constant (8.314 J/K.mol)
At the equilibrium: ΔG=0 and Q= Ka. So, we can calculate ΔGº by introducing the value of Ka:
⇒ 0 = ΔGº + RT ln Ka
ΔGº= - RT ln Ka
ΔGº= -8.314 J/K.mol x 298 K x ln (4.5 10⁻⁴)
ΔGº= 19092.8 J/mol
c)- According to the previous demonstation, at equilibrium ΔG= 0.
d)- In a non-equilibrium condition, we have Q which is calculated with the concentrations of products and reactions in a non equilibrium state:
ΔG= ΔGº + RT ln Q
Q= ((H⁺) (NO₂⁻))/(HNO₂)
Q= ( (5.9 10⁻² M) x (6.7 10⁻⁴ M) ) / (0.21 M)
Q= 1.88 10⁻⁴
We know that ΔGº= 19092.8 J/mol, so:
ΔG= ΔGº + RT ln Q
ΔG= 19092.8 J/mol + (8.314 J/K.mol x 298 K x ln (1.88 10⁻⁴)
ΔG= -2162.4 J/mol
Notice that ΔG<0, so the process is spontaneous in that direction.
Calcium Chloride because it is a type 1 so the the anion ends with -ide
Answer:
1.35 g
Explanation:
Data Given:
mass of Potassium Permagnate (KMnO₄) = 3.34 g
Mass of Oxygen: ?
Solution:
First find the percentage composition of Oxygen in Potassium Permagnate (KMnO₄)
So,
Molar Mass of KMnO₄ = 39 + 55 + 4(16)
Molar Mass of KMnO₄ = 158 g/mol
Calculate the mole percent composition of Oxygen in Potassium Permagnate (KMnO₄).
Mass contributed by Oxygen (O) = 4 (16) = 64 g
Since the percentage of compound is 100
So,
Percent of Oxygen (O) = 64 / 158 x 100
Percent of Oxygen (O) = 40.5 %
It means that for ever gram of Potassium Permagnate (KMnO₄) there is 0.405 g of Oxygen (O) is present.
So,
for the 3.34 grams of Potassium Permagnate (KMnO₄) the mass of Oxygen will be
mass of Oxygen (O) = 0.405 x 3.34 g
mass of Oxygen (O) = 1.35 g
The limiting reactant is chlorine (Cl2).
<u>Explanation</u>:
Limiting reactant is the amount of product formed which gets limited by the reagent without continuing it.
2 Al + 3 Cl2 ==> 2 AlCl3 represents the balanced equation.
Number of moles Al present = 34 g Al x 1 mole Al / 26.98 g
= 1.260 g moles of Al
Number of moles Cl2 present = 39 g Cl2 x 1 mole Cl2 / 35.45 g
= 1.10 g moles of Cl2
Dividing each reactant by it's coefficient in the balanced equation obtains:
1.260 moles Al / 2 = 0.63 g moles of Al
1.11 moles Cl2 / 3 = 0.36 g moles of Cl2
The reactant which produces a lesser amount of product is called as limiting reactant.
Here the Limiting reactant is Cl2.
Answer:
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