Answer:
The molality of isoborneol in camphor is 0.53 mol/kg.
Explanation:
Melting point of pure camphor= T =179°C
Melting point of sample = = 165°C
Depression in freezing point =
Depression in freezing point is also given by formula:
= The freezing point depression constant
m = molality of the sample
i = van't Hoff factor
We have: = 40°C kg/mol
i = 1 ( organic compounds)
The molality of isoborneol in camphor is 0.53 mol/kg.
Answer:
The Empirical Formula.
Explanation:
From the empirical formula and using the weight (in g) of a given substance, we can come up with the molecular formula which is the actual weight of a substance. Sometimes, we find that the empircal formula is the molecular formula.
<span>Answer is: pH of solution of sodium cyanide is 11.3.
Chemical reaction 1: NaCN(aq) → CN</span>⁻(aq)
+ Na⁺<span>(aq).
Chemical reaction 2: CN</span>⁻ +
H₂O(l) ⇄ HCN(aq) + OH⁻<span>(aq).
c(NaCN) = c(CN</span>⁻<span>)
= 0.021 M.
Ka(HCN) = 4.9·10</span>⁻¹⁰<span>.
Kb(CN</span>⁻) = 10⁻¹⁴ ÷
4.9·10⁻¹⁰ = 2.04·10⁻⁵<span>.
Kb = [HCN] · [OH</span>⁻]
/ [CN⁻<span>].
[HCN] · [OH</span>⁻<span>] =
x.
[CN</span>⁻<span>] = 0.021 M - x..
2.04·10</span>⁻⁵<span> = x² / (0.021 M
- x).
Solve quadratic equation: x = [OH</span>⁻<span>] = 0.00198 M.
pOH = -log(0.00198 M) = 2.70.
pH = 14 - 2.70 = 11.3.</span>