Answer:
79.04 L
Explanation:
We are given;
Initial Volume; V1 = 6.24L
Initial Pressure; P1 = 760 mm Hg
Final pressure; P2 = 60.0mm Hg
To solve for final volume, we will use Boyles law;
P1•V1 = P2•V2
Let's make V2 which is the final volume the subject;
V2 = (P1•V1)/P2
V2 = (760 × 6.24)/60
V2 = 79.04 L
The activation energy Ea can be related to rate constant (k) at temperature (T) through the equation:
ln(k2/k1) = Ea/R[1/T1 - 1/T2]
where :
k1 is the rate constant at temperature T1
k2 is the rate constant at temperature T2
R = gas constant = 8.314 J/K-mol
Given data:
k1 = 0.543 s-1; T1 = 25 C = 25+273 = 298 K
k2 = 6.47 s-1; T = 47 C = 47+273 = 320 K
ln(6.47/0.543) = Ea/8.314 [1/298 - 1/320]
2.478 = 2.774 *10^-5 Ea
Ea = 0.8934*10^5 J = 89.3 kJ
I believe the answer is A the 1st one
Those reactions in which Alkyl Halide reacts with the solvent without the involvement of any acid or base is called as
Solvolysis. In given problem <em>tert</em>-Butyl Bromide is a tertiary Alkyl Halide and we know well that tertiary alkyl halides undergo
SN¹ and
E¹ elimination reaction due to the formation of
stable tertiary carbocation. In given example after the formation of carbocation when Isopropyl act as
nucleophile it will produce
ether and when it acts as a
base it will produce
unsaturated compound. The reaction along with both products is shown below,