Answer : Carbon tetrachloride, 
will show the greatest freezing point lowering.
Explanation :
For non-electrolyte solution, the formula used for lowering in freezing point is,
where,
= lowering in freezing point
= molal depression constant
m = molality
As per question, the molality is same for all the non-electrolyte solution. So, the lowering in freezing point is depend on the only.
That means the higher the value of , the higher will be the freezing point lowering.
From the given non-electrolyte solutions, the value of of carbon tetrachloride is higher than the other solutions.
Therefore, Carbon tetrachloride, will show the greatest freezing point lowering.
Answer:
You cannot make observations if you are 57 seconds late into the lab.
Explanation:
The atomic nucleus can split by decay into 2 or more particles as a result of the instability of its atomic nucleus due to the fact that radioactive elements possess an unstable atomic nucleus.
Now, the primary particles which are emitted by radioactive elements in order to make them decay are alpha, beta & gamma particles.
The half life equation is;
N_t = N₀(½)^(t/t_½)
Where:
t = duration of decay
t_½ = half-life
N₀ = number of radioactive atoms initially
N_t = number of radioactive atoms remaining after decay over time t
We are given;
t = 57 secs
N₀ = 100 g
Now, half life of Nitrogen-16 from online sources is 7.2 seconds. t_½ = 7.2
Thus;
N_t = 100(1/2)^(57/7.2)
N_t = 0.4139g
We are told that In order to make observations, you require at least .5g of material.
The value of N_t you got is less than 0.5g, therefore you cannot make observations if you are 57 seconds late.
The structures of the isomers and the m/z values of their peaks are not given in the question. The complete question is provided in the attachment
Answer:
Compound 2 (2,5-dimethylhexane) will not have the peaks at 29 and 85 m/z
Explanation:
The fragmentation of molecules by electron ionization of mass spectrometer occurs according to Stevenson's Rule, which states that "The most probable fragmentation is the one that leaves the positive charge on the fragment with the lowest ionization energy". This is much like the Markovnikov's Rule in organic chemistry which has predicted the formation of most stable carbocation and the addition of hydrogen halide to it.
The mass spectra of compound 1 (2,4-dimethylhexane) will contain all the m/z values mentioned in the question. Each peak indicate towards homologous series of fragmentation product of the compound 1. The first peak can be attributed to ethyl carbocation (m/z = 29), with the increase of 14 units the next peak indicates towards propyl carbocation (m/z = 43) and onwards until molecular ion peak of 114 m/z.
Compound 2 (2,5-dimethylhexane) structure shows that the cleavage of C-C bond will not yield a stable ethyl and hexyl carbocation. Hence, no peaks will be observed at 29 and 85 m/z. The absence of these two peaks can be used to distinguish one isomer from the other.
1. Dmitri created groups of 3
2. John Newlands arranged the elements
3. Antoine Lavoisier divided them into catagories
4. Johann used patterns
hope this helped :)
From high temperature to low temperature.
