In order to determine the increase in boiling point of a solvent due to the presence of a solute, we use the formula:
ΔT = Kb * m * i
Here, Kb is a property of the solvent, so remains constant regardless of the solute. Moreover, because the concentration m has been fixed, this will also not be considered. In order to determine which solute will have the greatest effect, we must check i, the van't Hoff factor.
Simply stated, i is the number of ions that a substance produces when dissolved. Therefore, the solute producing the most ions will be the one causing the greatest change in boiling point temperature.
Answer:
- <em>The partial pressure of oxygen in the mixture is</em><u> 320.0 mm Hg</u>
Explanation:
<u>1) Take a base of 100 liters of mixture</u>:
- N: 60% × 100 liter = 60 liter
- O: 40 % × 100 liter = 40 liter.
<u>2) Volume fraction:</u>
At constant pressure and temperature, the volume of a gas is proportional to the number of molecules.
Then, the mole ratio is equal to the volume ratio. Callin n₁ and n₂, the number of moles of nitrogen and oxygen, respectively, and V₁, V₂ the volume of the respective gases you can set the proportion:
That means that the mole ratio is equal to the volume ratio, and the mole fraction is equal to the volume fraction.
Then, since the law of partial pressures of gases states that the partial pressure of each gas is equal to the mole fraction of the gas multiplied by the total pressure, you can draw the conclusion that the partial pressure of each gas is equal to the volume fraction of the gas in the mixture multiplied by the total pressure.
Then calculate the volume fractions:
- Volume fraction of a gas = volume of the gas / volume of the mixture
- N: 60 liter / 100 liter = 0.6 liter
- V: 40 liter / 100 liter = 0.4 liter
<u>3) Partial pressures:</u>
These are the final calculations and results:
- Partial pressure = volume fraction × total pressure
- Partial pressure of N = 0.6 × 800.0 mm Hg = 480.0 mm Hg
- Partial pressure of O = 0.4 × 800.0 mm Hg = 320.0 mm Hg
Answer:
Percent yield = 84.5 %
Explanation:
Given data:
Mass of methanol = 229 g
Actual yield of water = 219 g
Percent yield of water = ?
Solution:
Chemical equation:
2CH₃OH + 3O₂ → 2CO₂ + 4H₂O
Number of moles of methanol:
Number of moles = mass/ molar mass
Number of moles = 229 g/ 32 g/mol
Number of moles = 7.2 mol
Now we will compare the moles of water with methanol.
CH₃OH : H₂O
2 : 4
7.2 : 4/2×7.2 = 14.4 mol
Mass of water:
Mass = number of moles × molae mass
Mass = 14.4 mol × 18 g/mol
Mass = 259.2 g
Percent yield:
Percent yield = actual yield / theoretical yield × 100
Percent yield = 219 g / 259.2 g × 100
Percent yield = 84.5 %
A catalyst speeds up the rate of reaction so the answer is B.
The artificial fixation of nitrogen (N2) has enormous energy, environmental, and societal impact, the most important of which is the synthesis of ammonia (NH3) for fertilizers that help support nearly half of the world's population.
<h3>Artificial fixation of nitrogen</h3>
a) The equilibrium constant expression is Kp=PCH4 PH2 OP CO×PH 23.
(b) (i) As the pressure increases, the equilibrium will shift to the left so that less number of moles are produced.
(ii) For an exothermic reaction, with the increase in temperature, the equilibrium will shift in the backward direction.
(iii) When a catalyst is used, the equilibrium is not disturbed. The equilibrium is quickly attained
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