According to research, yes sulphur can penetrate glass.
1st and 4th options are suitable answers, as these 2 changes are not exactly physical changes as it cant return back to original form and as well as its not cooling, so I feel its 1st and 4th options
<span>1 Cu + 2 H</span>₂<span>SO</span>₄<span> = 1 CuSO</span>₄<span> + 2 H</span>₂<span>O + 1 SO</span>₂
Coefficient od CuSO₄ = 1
hope this helps!