Answer : The enthalpy of formation of is, -812.4 kJ/mole
Explanation :
According to Hess’s law of constant heat summation, the heat absorbed or evolved in a given chemical equation is the same whether the process occurs in one step or several steps.
According to this law, the chemical equation can be treated as ordinary algebraic expression and can be added or subtracted to yield the required equation. That means the enthalpy change of the overall reaction is the sum of the enthalpy changes of the intermediate reactions.
The formation of will be,
The intermediate balanced chemical reaction will be,
(1)
(2)
(3)
(4)
Now adding all the equations, we get the expression for enthalpy of formation of will be,
Therefore, the enthalpy of formation of is, -812.4 kJ/mole
PV=PV
(602.1 L)(2.77atm) = (110.6 L) (X atm)
1667.817=110.6X
15.07971971 atm = X
Rounds to 15.1 (sig figs so much fun)
Answer:
ΔG°rxn = +50.8 kJ/mol
Explanation:
It is possible to obtain ΔG°rxn of a reaction at certain temperature from ΔH°rxn and S°rxn, thus:
<em>ΔG°rxn = ΔH°rxn - T×S°rxn (1)</em>
In the reaction:
2 HNO3(aq) + NO(g) → 3 NO2(g) + H2O(l)
ΔH°rxn = 3×ΔHfNO2 + ΔHfH2O - (2×ΔHfHNO3 + ΔHfNO)
ΔH°rxn = 3×33.2kJ/mol + (-285.8kJ/mol) - (2×-207.0kJ/mol + 91.3kJ/mol)}
ΔH°rxn = 136.5kJ/mol
And S°:
S°rxn = 3×S°NO2 + S°H2O - (2×S°HNO3 + S°NO)
ΔH°rxn = 3×0.2401kJ/molK + (0.0700kJ/molK) - (2×0.146kJ/molK + 0.2108kJ/molK)
ΔH°rxn = 0.2875kJ/molK
And replacing in (1) at 298K:
ΔG°rxn = 136.5kJ/mol - 298K×0.2875kJ/molK
<em>ΔG°rxn = +50.8 kJ/mol</em>
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Only the Fe is unbalanced.
:)
The formula for molality---> m = moles solute/ Kg of solvent
the solute here is NH₃ because it's the one with less amount. which makes water the solvent.
1) let's convert the grams of NH₃ to moles using the molar mass
molar mass of NH₃= 14.0 + (3 x 1.01)= 17.03 g/ mol
15.0 g (1 mol/ 17.03 g)= 0.881 mol NH₃
2) let's convert the grams of water into kilograms (just divide by 1000)
250.0 g= 0.2500 kg
3) let's plug in the values into the molality formula
molality= mol/ Kg---> 0.881 mol/ 0.2500 kg= 3.52 m