Boric acid, H3BO3, in aqueous solution would only give out one H+ ion. As it is also produce OH ion and by hydrolysis it produces one proton. <span>All the boron compounds (BX3) are having only 6 valence electrons in it and should follow the octet rule by taking another electron.</span>
B(OH)3 + 2 H2O → B(OH)4− + H3O
Answer:
Approx. 4⋅g.
Explanation:
Moles of sulfuric acid =10.0⋅g98.08⋅g⋅mol−1=0.102⋅mol.
Now we have the molar quantity of sulfuric acid that react; we also have the stoichiometric equation that shows the molar equivalence of sulfuric acid, and lithium hydroxide.
Given the stoichiometry,
mass of water =0.102⋅mol×2×18.01.g.mol−1=??⋅g.
Why did I multiply the mass in this equation by 2? Am I pulling your leg?
Answer:
ΔG°rxn = +50.8 kJ/mol
Explanation:
It is possible to obtain ΔG°rxn of a reaction at certain temperature from ΔH°rxn and S°rxn, thus:
<em>ΔG°rxn = ΔH°rxn - T×S°rxn (1)</em>
In the reaction:
2 HNO3(aq) + NO(g) → 3 NO2(g) + H2O(l)
ΔH°rxn = 3×ΔHfNO2 + ΔHfH2O - (2×ΔHfHNO3 + ΔHfNO)
ΔH°rxn = 3×33.2kJ/mol + (-285.8kJ/mol) - (2×-207.0kJ/mol + 91.3kJ/mol)}
ΔH°rxn = 136.5kJ/mol
And S°:
S°rxn = 3×S°NO2 + S°H2O - (2×S°HNO3 + S°NO)
ΔH°rxn = 3×0.2401kJ/molK + (0.0700kJ/molK) - (2×0.146kJ/molK + 0.2108kJ/molK)
ΔH°rxn = 0.2875kJ/molK
And replacing in (1) at 298K:
ΔG°rxn = 136.5kJ/mol - 298K×0.2875kJ/molK
<em>ΔG°rxn = +50.8 kJ/mol</em>
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