Answer:
trans-1,3-pentadiene is more stable than 1,4-pentadiene due to presence of a conjugated double bond.
Explanation:
Here,
H(hydrogenated pdt.) is same for both 1,4-pentadiene and 1,3-pentadiene as they both produce pentane after hydrogenation
H(diene) depends on stability of diene.
More stable a diene, lesser will be it's H(diene) value (more neagtive).
trans-1,3-pentadiene is more stable than 1,4-pentadiene due to presence of a conjugated double bond.
Hence, is higher (less negative) for trans-1,3-pentadiene
Answer: the coefficient of volume expansion of glass = 0.86/(1000 * 52) = 0.00001654 per degree.
Explanation:
Original volume of mercury = 1000 cm3.
The final volume of mercury considering its volume expansion quotient = 1000 + 1000*(1.8*10^-4 *52) = 1000 + 9.36 = 1009.36 cm^3
Considering the glass as a non expanding substance, the complete excess volume of 9.36 cm3 of mercury should have overflown the container, but due to the expansion of glass, the capacity of mercury containment increases and so a lesser amount of mercury flows out.
The amount of mercury that actually flowed out = 8.50 cm3.
So, the expansion of the glass container = 9.36-8.50 = 0.86 cm3.
Using the formula for coefficient of expansion,
coefficient of volume expansion of glass = 0.86/(1000 * 52) = 0.00001654 per degree.
Answer:
283.725 kJ ⋅ mol − 1
Explanation:
C(s) + 2Br2(g) ⇒ CBr4(g) , Δ H ∘ = 29.4 kJ ⋅ mol − 1
Br2(g) ⇒ Br(g) , Δ H ∘ = 111.9 kJ ⋅ mol − 1
C(s) ⇒ C(g) , Δ H ∘ = 716.7 kJ ⋅ mol − 1
4*eqn(2) + eqn(3) ⇒ 2Br2(g) + C(s) ⇒ 4 Br(g) + C(g) , Δ H ∘ = 1164.3 kJ ⋅ mol − 1
eqn(1) - eqn(4) ⇒ 4 Br(g) + C(g) ⇒ CBr4(g) , Δ H ∘ = -1134.9 kJ ⋅ mol − 1
so,
average bond enthalpy is = 283.725 kJ ⋅ mol − 1
Answer:
speed=5cm/minute
Explanation:
Given at 2:00PM the hermit is at 10cm mark
Also given that the hermit reaches 60cm mark at 2:10PM
Therefore the time elapsed is 10 minutes =
the distance travelled by the hermit is 60-10=50cm=0.5m
We know that
speed = m/sec=5cm/minute