Increasing the pressure on a reaction involving reacting gases increases the rate of reaction. Changing the pressure on a reaction which involves only solids or liquids has no effect on the rate.
According to that Kc is an equilibrium constant in terms of molar concentrations.
and Kc = [C]^c *[D]^d / [A]^a * [B]^b >>>> (1)
in the general reaction:
aA + bB ↔ cC + dD
and, from our balanced equation:
CH4 + H2O ⇔ Co + 3H2 >>> (2)
So, we need to calculate the concentrations (molarity) of the products and reactants:
the Molarity of CH4 = no. of moles/volume (L)
and no. of moles = weigh / Molecular weight = 42.3 / 16 = 2.643 moles
so the molarity of CH4 = 2.643 / 5 = 0.528 molar
the molarity of H20 = (49.2 / 18) / 5 = 0.546 molar
the molarity of CO = (8.32/28) / 5 = 0.059 molar
the molarity of H2 = (2.63 / 2) / 5 = 0.263 molar
By substitution in (1) according to (2);
∴ Kc = [0.059]*[0.263]^3 / ( [0.528]*[0.546]) = 3.7 * 10 ^-3 >>>> (3)
Kp = Kc (RT)^(Δn) >>> (4)
where R is the gas constant = 0.0821,
and Δn is the change in moles in gas= (3(H2) + 1 (CO) - (1 H2O + 1 CH4) = 2
by substition in (4):
∴ Kp = 3.7*10^-3 (0.0821* 1000)^2= 24.939
Hey there!
Volume in mL :
1.25 * 1000 => 1250 mL
Density = 0.921 g/mL
Therefore:
Mass = density * volume
Mass = 0.921 * 1250
Mass = 1151.25 g