Answer:
See explanation and image attached
Explanation:
The Gilman reagent is a lithium and copper (diorganocopper) reagent with a general formula R2CuLi. R is an alkyl or aryl group.
They are useful in the synthesis of alkanes because they react with organic halides to replace the halide group with an R group.
In this particular instance, we intend to synthesize propylcyclohexane. The structure of the lithium diorganocopper (Gilman) reagent required is shown in the image attached to this answer.
Answer:
378mL
Explanation:
The following data were obtained from the question:
Pressure (P) = 99.19 kPa
Temperature (T) = 28°C
Number of mole (n) = 0.015 mole
Volume (V) =...?
Next, we shall convert the pressure and temperature to appropriate units. This is illustrated below:
For Pressure:
101.325 KPa = 1 atm
Therefore, 99.19 kPa = 99.19/101.325 = 0.98 atm
For Temperature:
T(K) = T(°C) + 273
T(°C) = 28°C
T(K) = 28°C + 273 = 301K.
Next we shall determine the volume of N2. The volume of N2 can be obtained by using the ideal gas equation as shown below:
PV = nRT
Pressure (P) = 0.98 atm
Temperature (T) = 301K
Number of mole (n) = 0.015 mole
Gas constant (R) = 0.0821atm.L/Kmol.
Volume (V) =...?
0.98 x V = 0.015 x 0.0821 x 301
Divide both side by 0.98
V = (0.015 x 0.0821 x 301) /0.98
V = 0.378 L
Finally, we shall convert 0.378 L to millilitres (mL). This is illustrated below:
1L = 1000mL
Therefore, 0.378L = 0.378 x 1000 = 378mL
Therefore, the volume of N2 collected is 378mL