Suppose you are trying to find the volume of a box based on the following measurements for the length, width, and height of the
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the reagents necessary to convert alcohol to ketone which involves oxidation of alcohols.
- Alcohol oxidation is a significant organic chemistry process. Secondary alcohols can be oxidized to produce ketones, while primary alcohols can be oxidized to produce aldehydes and carboxylic acids.
- In contrast, tertiary alcohols cannot be oxidized without the C-C bonds in the molecule being broken.
- In order to cause primary alcohols to oxidize into aldehydes
(dichromate)
/pyridine (Collins reagent)
- Chromium pyridinium compound (PCC)
- Dichromate of pyridinium (PDC, Cornforth reagent)
- Periodinane by Dess-Martin
- Oxalyl chloride with dimethylsulfoxide (DMSO) for Swern
- oxidation of secondary alcohols to ketones
- Chromium pyridinium compound (PCC)
- Dichromate of pyridinium (PDC, Cornforth reagent)
- Periodinane by Dess-Martin
- Oxalyl chloride and dimethyl sulfoxide (DMSO) (Swern oxidation)
/acetone (Jones oxidation)
- Acetone with aluminum isopropoxide (Oppenauer oxidation)
To learn more about oxidation of alcohols with the given link
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<u>Question:</u>
Identify the reagents necessary to achieve each of the following transformations
The given question is incomplete. The complete question is:
When 136 g of glycine are dissolved in 950 g of a certain mystery liquid X, the freezing point of the solution is 8.2C lower than the freezing point of pure X. On the other hand, when 136 g of sodium chloride are dissolved in the same mass of X, the freezing point of the solution is 20.0C lower than the freezing point of pure X. Calculate the van't Hoff factor for sodium chloride in X.
Answer: The vant hoff factor for sodium chloride in X is 1.9
Explanation:
Depression in freezing point is given by:
= Depression in freezing point
= freezing point constant
i = vant hoff factor = 1 ( for non electrolyte)
m= molality =
Now Depression in freezing point for sodium chloride is given by:
= Depression in freezing point
= freezing point constant
m= molality =
Thus vant hoff factor for sodium chloride in X is 1.9