Answer:
See explanation and image attached
Explanation:
The reaction of 1-bromo-2-tert-butylcyclohexane with potassium tert-butoxide is an elimination reaction that occurs by E2 mechanism.
The E2 reaction proceeds faster when the hydrogens are in an antiperiplanar position at an angle of 180 degrees.
This is only attainable in the trans isomer of 1-bromo-2-tert-butylcyclohexane. Hence trans 1-bromo-2-tert-butylcyclohexane reacts faster with potassium tert-butoxide
Answer : The rate of effusion of sulfur dioxide gas is 52 mL/s.
Solution :
According to the Graham's law, the rate of effusion of gas is inversely proportional to the square root of the molar mass of gas.
or,
..........(1)
where,
= rate of effusion of nitrogen gas =
= rate of effusion of sulfur dioxide gas = ?
= molar mass of nitrogen gas = 28 g/mole
= molar mass of sulfur dioxide gas = 64 g/mole
Now put all the given values in the above formula 1, we get:
Therefore, the rate of effusion of sulfur dioxide gas is 52 mL/s.