A hydrogen atom is an atom of the chemical element hydrogen. The electrically neutral atom contains a single positively charged proton and a single negatively charged electron bound to the nucleus by the Coulomb force.
It does not belong to any family of elements, and though it is a nonmetal, it appears on the left side of the periodic table with the metals. The other elements with it in Group 1 form the alkali metal family, but obviously, hydrogen does not belong with them.