Answer: There is not work done at the door because the door did not move.
Explanation: Work is defined as the movement done by a force.
So if you move to apply a force F in an object and you move it a distance D, the work applied on the object is
W = F*D
In this case, the secret agent pushes against the door, so there is a force, but the agent does not move the door, so D = 0, so there is no motion of the door, which implies that there is no work done at the door.