Lithium diisopropylamide [(CH3)2CH]2NLi, referred to as LDA, enjoys many uses as a strong base in synthetic organic chemistry. I
t is customarily prepared by the reaction of diisopropylamine [(CH3)2CH]2NH with butyllithium. Draw the products of the reactions in the appropriate boxes and select the acid, base, conjugate acid, and conjugate base. Be sure to answer all parts.
1 answer:
Answer:
Lithium diisopropylamide [(CH3)2CH]2NLi.
Explanation:
Lithium diisopropylamide (commonly abbreviated LDA) is a chemical compound with the molecular formula [(CH3)2CH]2NLi. It is used as a strong base and has been widely accepted due to its good solubility in non-polar organic solvents and non-nucleophilic nature. It is a colorless solid, but is usually generated and observed only in solution. It was first prepared by Hamell and Levine in 1950 along with several other hindered lithium diorganylamides to effect the deprotonation of esters at the α position without attack of the carbonyl group.
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Answer:- 0.273 kg
Solution:- A double replacement reaction takes place. The balanced equation is:
We have 0.29 L of 22% m/v aluminum nitrate solution. m/s stands for mass by volume. 22% m/v aluminium nitrate solution means 22 g of it are present in 100 mL solution. With this information, we can calculate the grams of aluminum nitrate present in 0.29 L.
= 63.8 g aluminum nitrate
From balanced equation, there is 1:3 mol ratio between aluminum nitrate and sodium chlorate. We will convert grams of aluminum nitrate to moles and then on multiplying it by mol ratio we get the moles of sodium chlorate that could further be converted to grams.
We need molar masses for the calculations, Molar mass of sodium chlorate is 106.44 gram per mole and molar mass of aluminum nitrate is 212.99 gram per mole.
=
sodium chlorate solution is 35% m/m. This means 35 g of sodium chlorate are present in 100 g solution. From here, we can calculate the mass of the solution that will contain 95.7 g of sodium chlorate and then the grams are converted to kg.
= 0.273 kg
So, 0.273 kg of 35% m/m sodium chlorate solution are required.