Explanation:
“The isomers butane and methyl propane have the same molecular formula and different properties”, this is because structural isomers usually have different properties to their parent.
Answer:
a)
b) entropy of the sistem equal to a), entropy of the universe grater than a).
Explanation:
a) The change of entropy for a reversible process:
The energy balance:
If the process is isothermical the U doesn't change:
The work:
If it is an ideal gas:
Solving:
Replacing:
Given that it's a compression: V2<V1 and ln(V2/V1)<0. So:
b) The entropy change of the sistem will be equal to the calculated in a), but the change of entropy of the universe will be 0 in a) (reversible process) and in b) has to be positive given that it is an irreversible process.
Answer:
a) Ba(OH)₂.8H₂O(s) + <em>2 </em>NH₄SCN(s) → Ba(SCN)₂(s) +<em>10</em> H₂O(l) + <em>2</em> NH₃(g)
b) 3.14g must be added
Explanation:
a) For the reaction:
Ba(OH)₂.8H₂O(s) + NH₄SCN(s) → Ba(SCN)₂(s) + H₂O(l) + NH₃(g)
As you see, there are 8 moles of water in reactants and 2 moles of oxygen in octahydrate, thus, water moles must be 10:
Ba(OH)₂.8H₂O(s) + NH₄SCN(s) → Ba(SCN)₂(s) +<em>10</em> H₂O(l) + NH₃(g)
To balance hydrogens, the other coefficients are:
Ba(OH)₂.8H₂O(s) + <em>2 </em>NH₄SCN(s) → Ba(SCN)₂(s) +<em>10</em> H₂O(l) + <em>2</em> NH₃(g)
b) As you see in the balanced reaction, 1 mole of barium hydroxide octahydrate reacts with 2 moles of NH₄SCN. 6.5g of Ba(OH)₂.8H₂O are:
6.5 g × (1mol / 315.48g) =<em> 0.0206moles of Ba(OH)₂.8H₂O</em>. Thus, moles of NH₄SCN that must be used for a complete reaction are:
0.0206moles of Ba(OH)₂.8H₂O × ( 2 mol NH₄SCN / 1 mol Ba(OH)₂.8H₂O) = <em>0.0412moles of NH₄SCN</em>. In grams:
0.0412moles of NH₄SCN × ( 76.12g / 1mol) = <em>3.14g must be added</em>
Answer:
The boiling point increases with increased pressure up to the critical point, where the gas and liquid properties become identical.