Answer: Because it's a combination of chemicals, vodka doesn't freeze at the same temperature as either water or alcohol. Of course, vodka will freeze, but not at the temperature of an ordinary freezer. This is because vodka contains enough alcohol to lower the freezing point of water below the -17°C of your typical freezer.
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Answer:
Depends how much water and the temperature of the water. To heat 1 mL of water by 1 degree C 1 cal of energy (4.184 Joules) is required. Assuming that the water is at 25 degrees C, to boil one litre (liter) of water you would require 75,000 cal or 313.8 kJ.