Answer:
A. (CH3)3C-I reacts by SN1 mechanism whose rate is independent of nucleophile reactivity.
Explanation:
We must recall that (CH3)3C-I is a tertiary alkyl halide. Tertiary alkyl halides preferentially undergo substitution reaction via SN1 mechanism.
In SN1 mechanism, the rate of reaction depends solely on the concentration of the alkyl halide (unimolecular mechanism) and is independent of the concentration of the nucleophile. As a result of this, both Br^- and Cl^- react at the same rate.
To work this out you do 400÷20=20
For a p type of semiconductor we need a dopant which is from 13th group in periodic table
Al , B, Ga, In Tl
So the correct element will be In : Indium
The other elements belongs to 15th group and hence will give n type semiconductor
