It is B, From the bottom of the pyramid to the top
Answer:
Answer: (1R,2S) / (1S, 2R) , (1R,2R) / (1S, 2S)
Explanation:
Sodium borohydride reduction of benzoin will give four possible stereo isomers out of which are (1R,2S) - (1S, 2R) isomers and (1R,2R) - (1S, 2S) isomers which are known as enantiomers.
In general enantiomers show single spot in the TLC as they do not show any difference in Rf value (i.e) (1R,2S) - (1S, 2R) isomers show only one spot although they are two compounds and also (1R,2R) - (1S, 2S) isomers also show one spot. That is the reason why you are observing two spots in the TLC ( of reaction mixture) other than starting materilal.
The volume of hydrogen gas that evolved is calculated as follows
by use of ideal gas equation
that is PV = nRT
P=745 mm hg
V= ?
R(gas constant)= 62.36 L.mm hg/mol.k
T= 20 + 273 = 293 k
n=number of moles which is calculated as follows
find the moles of Na used
= 0.52/23=0.023 moles
write the reacting equation
2Na +2H2O =2NaOH +H2
by use of reacting ratio between Na : H2 which is 2:1 therefore the mole of H2 = 0.023/2 =0.0115 moles
by making the volume the subject of the formula
v=nRT/P
V= (0.0115 x 62.36 x 293) / 745 = 0.283 L
Answer:
enantiomers
Explanation:
L and D stand for levorotatory and dextrorotatory respectively. A levorotatory molecule will rotate the plane of plane polarised light left and a dextrorotatory molecule will rotate the plane of plane polarised light right. L and D molecules are non superimposable mirror image of each other. Therefore they are also known as enantiomers.
