Answer : The time taken for the reaction is, 28 s.
Explanation :
Expression for rate law for first order kinetics is given by :
where,
k = rate constant = 0.0632
t = time taken for the process = ?
= initial amount or concentration of the reactant = 1.28 M
= amount or concentration left time 't' =
Now put all the given values in above equation, we get:
Therefore, the time taken for the reaction is, 28 s.
Answer:
= 25.05°C
Explanation:
Given:
the value of ΔHcomb (heat of combustion) for dimethylphthalate (C10H10O4) is = 4685 kJ/mol.
mass = 0.905g of dimethylphthalate
molar mass = 194.18g dimethylphthalate
number of moles of dimethylphthalate = ???
= 21.5°C
= 6.15 kJ/°C
= ???
since we have our molar mass and mass of dimethylphthalate ;we can determine the number of moles as;
0.905g of dimethylphthalate ×
number of moles of dimethylphthalate = 0.000466 moles
Heat released = moles of dimethylphthalate × heat of combustion
= 0.000466 moles × 4685 kJ
= 21.84 kJ
∴ Heat absorbed by the calorimeter =
21.84 kJ =6.15 kJ/°C
21.84 KJ =
21.84 KJ = - 132.225 kJ
21.84 KJ + 132.225 kJ =
154.065 kJ =
=
=25.05°C
<u>Answer:</u>
<u>For A:</u> The for the given reaction is
<u>For B:</u> The for the given reaction is 1642.
<u>Explanation:</u>
The given chemical reaction follows:
The expression of for the above reaction follows:
We are given:
Putting values in above equation, we get:
Hence, the for the given reaction is
Relation of with is given by the formula:
where,
= equilibrium constant in terms of partial pressure =
= equilibrium constant in terms of concentration = ?
R = Gas constant =
T = temperature = 500 K
= change in number of moles of gas particles =
Putting values in above equation, we get:
Hence, the for the given reaction is 1642.
D. Electrons orbit in a fixed shell