Answer:
K(48.5°C) = 1.017 E-8 s-1
Explanation:
- CH3Cl + H2O → CH3OH + HCl
at T1 = 25°C (298 K) ⇒ K1 = 3.32 E-10 s-1
at T2 = 48.5°C (321.5 K) ⇒ K2 = ?
Arrhenius eq:
- K(T) = A e∧(-Ea/RT)
- Ln K = Ln(A) - [(Ea/R)(1/T)]
∴ A: frecuency factor
∴ R = 8.314 E-3 KJ/K.mol
⇒ Ln K1 = Ln(A) - [Ea/R)*(1/T1)]..........(1)
⇒ Ln K2 = Ln(A) - [(Ea/R)*(1/T2)].............(2)
(1)/(2):
⇒ Ln (K1/K2) = (Ea/R)* (1/T2-1/T1)
⇒ Ln (K1/K2) = (116 KJ/mol/8.3134 E-3 KJ/K.mol)*(1/321.5 K - 1/298 K)
⇒ Ln (K1/K2) = (13952.37 K)*(- 2.453 E-4 K-1)
⇒ Ln (K1/K2) = - 3.422
⇒ K1/K2 = e∧(-3.422)
⇒ (3.32 E-10 s-1)/K2 = 0.0326
⇒ K2 = (3.32 E-10 s-1)/0.0326
⇒ K2 = 1.017 E-8 s-1
Answer:
W = -120 KJ
Explanation:
Since the piston–cylinder assembly undergoes an isothermal process, then the temperature is constant.
Thus; T1 = T2 = 400K
change in entropy; ΔS = −0.3 kJ/K
Formula for change in entropy is written as;
ΔS = Q/T
Where Q is amount of heat transferred.
Thus;
Q = ΔS × T
Q = -0.3 × 400
Q = -120 KJ
From the first law of thermodynamics, we can find the workdone from;
Q = ΔU + W
Where;
ΔU is Change in the internal energy
W = Work done
Now, since it's an ideal gas model, the change in internal energy is expressed as;
ΔU = m•C_v•ΔT
Where;
m is mass
C_v is heat capacity at constant volume
ΔT is change in temperature
Now, since it's an isothermal process where temperature is constant, then;
ΔT = T2 - T1 = 0
Thus;
ΔU = m•C_v•ΔT = 0
ΔU = 0
From earlier;
Q = ΔU + W
Thus;
-120 = 0+ W
W = -120 KJ
Answer:
A, Animal-like protists are called protozoa. ... Like animals, they can move, and they are heterotrophs. That means they eat things outside of themselves instead of producing their own food
Explanation:
2-naphthol, based on its structure will be least soluble in water.
2-Naphthol, or β-naphthol, is a fluorescent, colorless (or occasionally yellow) crystalline solid with the formula C10H7OH. It is an isomer of 1-naphthol, differing by the location of the hydroxyl group on the naphthalene ring. The naphthols are naphthalene homologues of phenol, but more reactive. Both isomers are soluble in simple alcohols, ethers, and chloroform. 2-Naphthol is a widely used intermediate for the production of dyes and other compounds.
