All categories

3 years ago

Arranges the following molecules in order of increasing dipole moment: H2O, H2S, H2Te, H2Se.

Chemistry

1 answer:

erastova [34]3 years ago

7 0

Explanation:

Dipole moment is defined as the measurement of the separation of two opposite electrical charges.

$H_{2}O$ is a bent shaped molecule with a dipole moment of 1.87.

$H_{2}S$ is also a bent shaped molecule with a dipole moment of 1.10.

$H_{2}Te$ is a also a bent shaped molecule and has a negligible dipole moment.

$H_{2}Se$ has a dipole moment of 0.29.

Therefore, given molecules are arranged according to their increasing dipole moment as follows.

$H_{2}Te$ < $H_{2}Se$ < $H_{2}S$ < $H_{2}O$

You might be interested in

Please do these questions, will give brainliest

Nata [24]

Answer:

1.c 2.a.3.d 4.a

Explanation:

that is tge answer

3 0

2 years ago

The half-reaction at the cathode in an electrochemical cell is given below.

olga55 [171]

Explanation:

a) Anode:

Cathode :

c) As , the reaction is spontaneous.

Explanation:

a) Here Ni undergoes oxidation by loss of electrons, thus act as anode. Hydrogen undergoes reduction by gain of electrons and thus act as cathode.

Anode:

Cathode :

b) The representation is given by writing the anode on left hand side followed by its ion with its molar concentration. It is followed by a slat bridge. Then the cathodic ion with its molar concentration is written and then the cathode.

Where both are standard reduction potentials.

= +ve, reaction is spontaneous

= -ve, reaction is non spontaneous

= 0, reaction is in equilibrium

Thus as , the reaction is spontaneous.

d) The standard emf of a cell is related to Gibbs free energy by following relation:

= standard gibbs free energy

n= no of electrons gained or lost

F= faraday's constant

= standard emf

Thus value of Gibbs free energy is -48250 Joules.

7 0

2 years ago

Given the following: [G3P] = 1.5x10-5M; [BPG] = 3.0x10-3M ; [NAD+] = 1.2x10-5M; [NADH]=1.0x10-4 ; [HPO42-]= 1.2x10-5 M; pH = 7.5

mel-nik [20]

Answer: The given reaction is non-spontaneous in nature.

Explanation:

To calculate the $H^+$ concentration, we use the equation:

$pH=-\log[H^+]$

We are given:

pH of the solution = 7.5

$7.5=-\log [H^+]$

$[H^+]=10^{-7.5)=3.1\times 10^{-8}M$

For the given chemical equation:

$\text{Glyceraldehyde3-phosphate }+NAD^++HPO_4^{2-}\rightarrow \text{1,3-Biphosphoglycerate }+NADH+H^+$

The equation used to Gibbs free energy of the reaction follows:

$\Delta G=\Delta G^o+RT\ln K_{eq}$

where,

$\Delta G$ = free energy of the reaction

$\Delta G^o$ = standard Gibbs free energy = 6.3 kJ/mol = 6300 J/mol (Conversion factor: 1kJ = 1000J)

R = Gas constant = 8.314J/K mol

T = Temperature = $25^oC=[273+25]K=298K$

$K_{eq}$ = Ratio of concentration of products and reactants = $\frac{[BPG][NaDH][H^+]}{[G_3P][NAD^+][HPO_4^{2-}]}$

$[BPG]=3.0\times 10^{-3}M$

$[NADH]=1.0\times 10^{-4}M$

$[H^+]=3.1\times 10^{-8}M$

$[G_3P]=1.5\times 10^{-5}M$

$[NAD^+]=1.2\times 10^{-5}M$

$[HPO_4^{2-}]=1.2\times 10^{-5}M$

Putting values in above equation, we get:

$\Delta G=6300J/mol+(8.314J/K.mol\times 298K\times \ln (\frac{(3.0\times 10^{-3})\times (1.0\times 10^{-4})\times (3.1\times 10^{-8})}{(1.5\times 10^{-5})\times (1.2\times 10^{-5})\times (1.2\times 10^{-5})}))\\\\\Delta G=9917.02J/mol=9.92kJ/mol$

For the reaction to be spontaneous, the Gibbs free energy of the reaction must come out to be negative.

As, the Gibbs free energy of the reaction is positive. The reaction is said to be non-spontaneous.

Hence, the given reaction is non-spontaneous in nature.

4 0

2 years ago

I just need help on c-g. The whole question is there in case anyone needs it.

Elza [17]

Answer:

(g) No effect on ΔH

Step-by-step explanation:

(c) Kc at 125 °C

In Part (a) one molecule of XY dissociated into one X and one Y.

XY ⇌ X + Y

I: 10 0 0

C: -1 +1 +1

E: 9 1 1

Kc = {[X][Y]}/[XY] = (1 × 1)/9 = ⅑ = 0.11

(d) ΔH

ΔH is a constant that is characteristic of the reaction.

ΔH = -24.5 kJ·mol⁻¹

(e) Effect of temperature on concentrations

If ΔH is negative, the reaction is exothermic.

Heat is a product of the reaction, so we can write the equation as

XY ⇌ X + Y + heat

If we lower the temperature, we are removing heat from the system.

Le Châtelier's Principle states that if you apply a stress to a system at equilibrium, it will respond by trying to relieve the stress.

We applied a stress by removing heat, so the system responds by producing more heat. The position of equilibrium moves to the right, and more products will form.

The diagram might look like the one below.

(f) Effect of temperature on Kc

Kc = [Products]/[Reactants]

We are increasing [Products] and decreasing [Reactants].

If you increase the numerator and decrease the denominator, you increase the value of the quotient.

The value of the equilibrium constant increases when the temperature decreases.

(g) Effect of temperature on ΔH

Decreasing the temperature has no effect on ΔH, because the enthalpies of the reactants and products are properties of the substances themselves. They do not depend on the temperature.

7 0

2 years ago

Acid chlorides can be converted into primary amines with the loss of a single carbon atom via the Curtius rearrangement. The rea

Marat540 [252]

Answer:

Find the given attachment.

5 0

2 years ago