Answer:
c. 8.1 L
Explanation:
Given that:-
Moles of oxygen gas = 0.50 mol
According to the reaction shown below as:-
3 moles of oxygen gas on reaction gives 2 moles of ozone
Also,
1 mole of oxygen gas on reaction gives 2/3 moles of ozone
So,
0.50 mole of oxygen gas on reaction gives moles of ozone
Moles of ozone = 0.3333 mol
Pressure = 1 atm
Temperature = 25.0 °C
The conversion of T( °C) to T(K) is shown below:
T(K) = T( °C) + 273.15
So,
T = (25.0 + 273.15) K = 298.15 K
Volume = ?
Using ideal gas equation as:
PV=nRT
where,
P is the pressure
V is the volume
n is the number of moles
T is the temperature
R is Gas constant having value = 0.0821 L.atm/K.mol
Applying the equation as:
1 atm × V = 0.3333 mol × 0.0821 L.atm/K.mol × 298.15 K
⇒V = 8.1 L
the balanced equation for the formation of ammonia is
N₂ + 3H₂ ---> 2NH₃
molar ratio of N₂ to NH₃ is 1:2
mass of N₂ reacted is 8.0 g
therefore number of N₂ moles reacted is - 8.0 g / 28 g/mol = 0.286 mol
according to the molar ratio,
1 mol of N₂ will react to give 2 mol of NH₃, assuming nitrogen is the limiting reactant
therefore 0.286 mol of N₂ should give - 2 x 0.286 mol = 0.572 mol of NH₃
therefore mass of NH₃ formed is - 0.572 mol x 17 g/mol = 9.72 g
a mass of 9.72 mol of NH₃ is formed
The question requires us to explain the differences in radii of neutral atoms, cations and anions.
To answer this question, we need to keep in mind that a neutral atom presents the same number of protons (positive particles) and electrons (negative particles). Another important information is that the protons are located in the nucleus of the atom, while the electrons are around the nucleus. Also, there is an electrostatic force between protons and electrons, which means that they the protons tend to attract the electrons to the nucleus.
While a neutral atom presents the same number of protons and electrons, a cation is an ion with positive charge, which means it has lost one or more electrons. In a cation, the balance between protons and electrons doesn't exist anymore: now, there is more positive than negative charge (more protons than electrons), and the overall attractive force that the protons have for the electrons is increased. As a result, the electrons stay closer to the nucleus and the radius of a cation is smaller than the neutral atom from which it was derived.
On the other side, anions present negative charge, which means they have received electrons. Similarly to cations, the balance between protons and electrons doesn't exist anymore, but in this case, there are more electrons than protons. In an anion, the overall attractive force that the protons have for the electrons is decreased. As a result, the electrons are "more free" to move and, as they are not so attracted to the nucleus, they tend to stay farther from the positive nucleus compared to the neutral atom - because of this, the radius of an anion is larger than the neutral atom from which it was derived.