Answer:
The correct answer is entropy change of the surrounding plus the entropy change of the system must be positive.
Explanation:
The term entropy is a state function.Entropy can be defined as the disorder or randomness of the molecules in a system.
A spontaneous reaction is a type of reaction which deals with the release of free energy.The change of free energy in case of spontaneous reaction is always negative.
According to the second law of thermodynamics a spontaneous reaction will occur in a system if the total entropy of both system and surrounding increases during the reaction.
The volume of the 0.279 M Ca(OH)₂ solution required to neutralize 24.5 mL of 0.390 M H₃PO₄ is 51.4 mL
<h3>Balanced equation </h3>
2H₃PO₄ + 3Ca(OH)₂ —> Ca₃(PO₄)₂ + 6H₂O
From the balanced equation above,
- The mole ratio of the acid, H₃PO₄ (nA) = 2
- The mole ratio of the base, Ca(OH)₂ (nB) = 3
<h3>How to determine the volume of Ca(OH)₂ </h3>
- Molarity of acid, H₃PO₄ (Ma) = 0.390 M
- Volume of acid, H₃PO₄ (Va) = 24.5 mL
- Molarity of base, Ca(OH)₂ (Mb) = 0.279 M
- Volume of base, Ca(OH)₂ (Vb) =?
MaVa / MbVb = nA / nB
(0.39 × 24.5) / (0.279 × Vb) = 2/3
9.555 / (0.279 × Vb) = 2/3
Cross multiply
2 × 0.279 × Vb = 9.555 × 3
0.558 × Vb = 28.665
Divide both side by 0.558
Vb = 28.665 / 0.558
Vb = 51.4 mL
Thus, the volume of the Ca(OH)₂ solution needed is 51.4 mL
Learn more about titration:
brainly.com/question/14356286
Answer:
Explanation:
M(s) → M (g ) + 20.1 kJ --- ( 1 )
X₂ ( g ) → 2X (g ) + 327.3 kJ ---- ( 2 )
M( s) + 2 X₂(g) → M X₄ (g ) - 98.7 kJ ----- ( 3 )
( 3 ) - 2 x ( 2 ) - ( 1 )
M( s) + 2 X₂(g) - 2 X₂ ( g ) - M(s) → M X₄ (g ) - 98.7 kJ - 2 [ 2X (g ) + 327.3 kJ ] - M (g ) - 20.1 kJ
0 = M X₄ (g ) - 4 X (g ) - M (g ) - 773.4 kJ
4 X (g ) + M (g ) = M X₄ (g ) - 773.4kJ
heat of formation of M X₄ (g ) is - 773.4 kJ
Bond energy of one M - X bond = 773.4 / 4 = 193.4 kJ / mole
Answer:
because they cannot keep their body temperature constant.