Answer:
These glucose molecules are stored in the liver and muscles to be used for fuel, especially during physical activity. Carbohydrates improve athletic performance by delaying fatigue and allowing an athlete to compete at higher levels for longer. nutrients, such as fat or muscle protein, are utilized to make energy.
Explanation:
Answer:
0.4 M
Explanation:
Equilibrium occurs when the velocity of the formation of the products is equal to the velocity of the formation of the reactants. It can be described by the equilibrium constant, which is the multiplication of the concentration of the products elevated by their coefficients divided by the multiplication of the concentration of the reactants elevated by their coefficients. So, let's do an equilibrium chart for the reaction.
Because there's no O₂ in the beginning, the NO will decompose:
N₂(g) + O₂(g) ⇄ 2NO(g)
0.30 0 0.70 Initial
+x +x -2x Reacts (the stoichiometry is 1:1:2)
0.30+x x 0.70-2x Equilibrium
The equilibrium concentrations are the number of moles divided by the volume (0.250 L):
[N₂] = (0.30 + x)/0.250
[O₂] = x/0.25
[NO] = (0.70 - 2x)/0.250
K = [NO]²/([N₂]*[O₂])
K =
7.70 = (0.70-2x)²/[(0.30+x)*x]
7.70 = (0.49 - 2.80x + 4x²)/(0.30x + x²)
4x² - 2.80x + 0.49 = 2.31x + 7.70x²
3.7x² + 5.11x - 0.49 = 0
Solving in a graphical calculator (or by Bhaskara's equation), x>0 and x<0.70
x = 0.09 mol
Thus,
[O₂] = 0.09/0.250 = 0.36 M ≅ 0.4 M
Answer:
Four possible isomers (1–4) for the natural product essramycin. The structure of compound 1 was attributed to essramycin by 1H NMR, 13C NMR, HMBC, HRMS, and IR experiments.
Explanation:
Three synthetic routes were used to prepare all four compounds (Figure 2A). All three reactions utilize 2-(5-amino-4H-1,2,4-triazol-3-yl)-1-phenylethanone (5) as the precursor, whereas each uses different esters (6–8) to construct the pyrimidinone ring. Isomer 1 was prepared by reaction A, which used triazole 5 and ethyl acetoacetate (6) in acetic acid. This was the reaction used in syntheses of essramycin by the Cooper and Moody laboratories.3,4 Reaction B produced compound 2 (minor product) and compound 3 (major product), which were separated chromatographically. This reaction allowed reagent 5 to react with ethyl 3-ethoxy-2-butenoate (7) in the presence of sodium in methanol, under reflux for 24 h. Compound 4 was prepared by reaction C, which was obtained by reflux of 5 and methyl 2-butynoate (8) in n-butanol.