Following chemical reaction is involved upon titration of Ca(OH)2 with HCl,
Ca(OH)2 + 2HCl ↔ CaCL2 + 2H2O
Above is an example of acid-base titration to generate salt and water. Here, H+ ions of acid (HCl) combines with OH- (ions) of base [Ca(OH)2] to generated H2O
Given,
concentration of HCl = 0.0199 M
Total volume of HCl consumed during titration = 16.08 mL = 16.08 X 10^(-3) L
∴, number of moles of H+ consumed = Molarity X Vol. of HCl (in L)
= 0.0199 X 16.08 X 10^(-3)
= 3.1999 X 10^-4 mol
Thus, total number of moles of [OH-] ions present initial = 3.1999 X 10-4 mol
So, initial conc. [OH-] ion = =
= 0.03199 M
Following reaction occurs in the given electrochemical system:
→ Fe +
Thus, under standard conditions
E(0) = E(0) Fe2+/Fe - E(0) Zn2+/Zn
where,
= standard reduction potential of Fe2+/Fe = -0.44 v
= standard reduction potential of Zn2+/Zn = -0.763 v
E(0) = 0.323 v
now, we know that, ΔG(0) =-nFE(0) ............... (1)
Also, Δ
On equating and rearranging equation 1 and 2, we get
K = exp(
)= exp (
) = 8.46 x
Because water vapor, uncontained, will diffuse out into the atmosphere and is not close enough to condense back into the liquid water, so no equilib. can be established.