Answer:
In thermodynamics, the Joule–Thomson effect describes the temperature change of a real gas or liquid when it is forced through a valve or porous plug while keeping it insulated so that no heat is exchanged with the environment. This procedure is called a throttling process or Joule–Thomson process
C. A nearly identical image.
It actually depends on the percentage of the concentration give. Percentages can be expressed as %mass/mass, %volume/volume or %mass/volume. To keep things simple, let's just assume that it is in %volume/volume. Thus, 13% of 520 mL is pure acid.
Volume of pure acid = 520*0.13 = 67.6 mL
Answer:
A)
1. Reaction will shift rightwards towards the products.
2. It will turn green.
3. The solution will be cooler..
B) It will turn green.
Explanation:
Hello,
In this case, for the stated equilibrium:
In such a way, by thinking out the Le Chatelier's principle, we can answer to each question:
A)
1. If potassium bromide, which adds bromide ions, is added more reactant is being added to the solution, therefore, the reaction will shift rightwards towards the products.
2. The formation of the green complex is favored, therefore, it will turn green.
3. The solution will be cooler as heat is converted into "cold" in order to reestablish equilibrium.
B) In this case, as the heat is a reactant, if more heat is added, more products will be formed, which implies that it will turn green.
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Answer:
Explanation has been given below.
Explanation:
- Chloroform has three polar C-Cl bonds. Methylene chloride has two polar C-Cl bonds. So it is expected that chloroform should be more polar and posses higher dipole moment than methylene chloride.
- Two factors are liable for the opposite trend observed in dipole moments of methylene chloride and chloroform.
- First one is the number of hyperconjugative hydrogen atoms present in a molecule. Hyperconjugation occurs with vacant d-orbital of Cl atom. Hyperconjugation amplifies charge separation in a molecule resulting higher dipole moment.
- Methylene chloride has two hyperconjugative hydrogen atoms and chloroform has one hyperconjugative hydrogen atom.Therefore methylene chloride should have higher charge separation as compared to chloroform.
- Second one is induction of opposite polarity in a C-Cl bond by another C-Cl bond in a molecule. Higher the opposite induction of polarity, lower the charge separation in a molecule and hence lower the dipole moment of a molecule.
- Chloroform has three C-Cl bonds and methylene chloride has two C-Cl bonds. Therefore opposite induction is higher for chloroform resulting it's lower dipole moment.