Answer:
The answer is C I think..
Answer : The work, heat during the process and the change of entropy of the gas are, 0 J, 3333.003 J and -10 J respectively.
Explanation :
(a) At constant volume condition the entropy change of the gas is:
We know that,
The relation between the for an ideal gas are :
As we are given :
Now we have to calculate the entropy change of the gas.
(b) As we know that, the work done for isochoric (constant volume) is equal to zero.
(C) Heat during the process will be,
Therefore, the work, heat during the process and the change of entropy of the gas are, 0 J, 3333.003 J and -10 J respectively.
Answer:
i = 2.483
Explanation:
The vapour pressure lowering formula is:
Pₐ = Xₐ×P⁰ₐ <em>(1)</em>
For electrolytes:
Pₐ = nH₂O / (nH₂O + inMgCl₂)×P⁰ₐ
Where:
Pₐ is vapor pressure of solution (<em>0.3624atm</em>), nH₂O are moles of water, nMgCl₂ are moles of MgCl₂, i is Van't Hoff Factor, Xₐ is mole fraction of solvent and P⁰ₐ is pressure of pure solvent (<em>0.3804atm</em>)
4.5701g of MgCl₂ are:
4.5701g ₓ (1mol / 95.211g) = 0.048000 moles
43.238g of water are:
43.238g ₓ (1mol / 18.015g) = 2.400 moles
Replacing in (1):
0.3624atm = 2,4mol / (2.4mol + i*0.048mol)×0.3804atm
0.3624atm / 0.3804atm = 2,4mol / (2.4mol + i*0.048mol)
2.4mol + i*0.048mol = 2.4mol / 0.9527
2.4mol + i*0.048mol = 2.5192mol
i*0.048mol = 2.5192mol - 2.4mol
i = 0.1192mol / 0.048mol
<em>i = 2.483</em>
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I hope it helps!
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1) ΔrH = 2mol·ΔfH(NO) - (ΔfH(O₂) + ΔfH(N₂)).
ΔrH = 2 mol · 90.3 kJ/mol - (0 kJ/mol + 0 kJ/mol).
ΔrH = 180.6 kJ.
2) ΔS = 2mol·ΔS(NO) - (ΔS(O₂) + ΔS(N₂)).
ΔS = 2mol · 210.65 J/mol·K - (1mol · 205 J/mol·K + 1 mol · 191.5 J/K·mol).
ΔS = 24.8 J/K.
3) ΔG = ΔH - TΔS.
55°C: ΔG = 180.6 kJ - 328.15 K · 24.8 J/K = 172.46 kJ.
2570°C: ΔG = 180.6 kJ - 2843.15 K · 24.8 J/K = 110.09 kJ.
3610°C: ΔG = 180.6 kJ - 3883.15 K · 24.8 J/K = 84.29 kJ.