<u>Answer:</u> The correct answer is Option B.
<u>Explanation:</u>
Valence electrons are defined as the electrons which are present in outermost shell of an atom. This is determined by the electronic configuration of an element.
For the given options:
<u>Option A:</u> Vanadium (V)
The atomic number of this atom is 23 and number of electrons that are present are 23. The electronic configuration of vanadium is:
This element does not have 3 electrons in 4d-subshell.
<u>Option B:</u> Niobium (Nb)
The atomic number of this atom is 41 and number of electrons that are present are 41. The electronic configuration of niobium is:
This element have 3 electrons in 4d-subshell.
<u>Option C:</u> Copper (Cu)
The atomic number of this atom is 29 and number of electrons that are present are 29. The electronic configuration of copper is:
This element does not have 3 electrons in 4d-subshell.
<u>Option D:</u> Thallium (Tl)
The atomic number of this atom is 81 and number of electrons that are present are 81. The electronic configuration of thallium is:
This element does not have 3 electrons in 4d-subshell.
Hence, the correct answer is Option B.