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0.012moldm⁻³
Explanation:
Given parameters:
Mass of AgNO₃ = 1000mg
Volume of water = 500mL
Unknown:
Molarity of solution = ?
Solution:
The molarity of a solution is the number of moles of a solute dissolved in volume of solvent.
Molarity =
Number of moles of AgNO₃ = ?
Number of moles =
Molar mass of AgNO₃ = 108 + 14 + 3(16) = 170g/mol
convert mass to g;
1000mg = 1g
Number of moles = = 0.00588moles
convert the given volume to dm³;
1000mL = 1dm³;
500mL = 0.5dm³
Now solve;
Molarity = = 0.012moldm⁻³
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Empirical formula of ionic compound is FeO. In which the composition of atoms is 1 : 1.
Empirical formula of an ionic compound is defined as the formula which gives whole number ratio of atoms of various elements present in molecule of compund.
mass of iron in compound = 34.95 g
molar mass of iron = 55.8 g
mass of oxygen in compound = 15.05 g
molar mass of oxygen = 32 g
number of moles of iron present in the compound are ratio of mass of iron in compound/ molar mass of iron
number of moles of iron in compound= 34.95 / 55.8 = 0.6263 ~ 1
number of moles oxygen in compound= 15.05/ 32 = 0.473 ~ 0.5
the ratio of the number of oxygen atoms to number of iron atoms present in one formula unit of iron compund is 2×0.5 / 1 = 1 : 1
Hence , the required empirical formula of iron compound is FeO.
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<span>The nitartion of methyl benzoate is expected to proceed as given in the equation below:
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In methyl benzoate there are 3 types of 1 H proton. The two ortho to the C=O group is a doublet at 8 ppm the 2 metal to the C=O is a multiple at 7.5 ppm and one para to the C=O is a multiplet at 7.5 ppm.
On nitration the ortho will probably show two signal one being a single with 3 proton integration and one a doublet with 1 H integration
The meta will show a highly down field singlet (coresponding to 1 proton), two unequal doublets (corresponding to 1 H each) and one multiplets (corresponding to 1H). This is the major product as seen from the 1H NMR.
The para isomer will come as two doublets which will be very close to each other there is a small signal for this set between 8.2 and 8.3 ppm.