The answer is: when the aim is to show electron distributions in shells
An orbital notation is more appropriate if you want to show how the electrons of an atom are distributed in each subshell. This is because there are some atoms that have special electronic configurations that aren't obvious in just written configurations.
Water
Water is a compound because it is made from more than one kind of element (oxygen and hydrogen).
We are told that KOH is being used to completely neutral H₂SO₄ according to the following reaction:
KOH + H₂SO₄ → H₂O + KHSO₄
If KOH can completely neutralize H₂SO₄, then there must be an equal amount of moles of each as they are in a 1:1 ratio:
0.025 L x 0.150 mol/L = .00375 mol KOH
0.00375 mol KOH x 1 mole H₂SO₄/1 mole KOH = 0.00375 mol H₂SO₄
We are told we have 15 mL of H₂SO₄ initially, so now we can find the original concentration:
0.00375 mol / 0.015 L = 0.25 mol/L
The concentration of H₂SO₄ being neutralized is 0.25 M.