Answer: 4 valence electrons, Silicon, Si, 14, 28.0855, 14
Explanation:
I might not be right but I think the empirical formula is NO2
When the same species undergoes both oxidation and reduction in a single redox reaction, this is referred to as a disproportionation. Therefore, divide it into two equal reactions.
NO2→NO^−3
NO2→NO
and do the usual changes
First, balance the two half reactions:
3. NO2 +H2O →NO^−3 + 2 H^+ + e−
4. NO2 +2 H^+ + 2e− → NO + H2O
Now multiply one or both half-reactions to ensure that each has the same number of electrons. Here, Eqn (3) x 2 results in each half-reaction having two electrons:
5. 2 NO2 + 2 H2O → 2 NO^−3 + 4H^+ + 2e−
Now add Eqn 4 and 5 (the electrons now cancel each other):
3NO2 + 2H^+ + 2H2O → NO + 2 NO−3 + H2O + 4H+
and cancel terms that’s common to both sides:
3NO2 + H2O → NO + 2NO^−3 + 2H+
This is the net ionic equation describing the oxidation of NO2 to NO3 in basic solution.
Learn more about balancing equation here:
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The answer is Ka = 1.00x10^-10.
Solution:
When given the pH value of the solution equal to 11, we can compute for pOH as
pOH = 14 - pH = 14 - 11.00 = 3.00
We solve for the concentration of OH- using the equation
[OH-] = 10^-pOH = 10^-3 = x
Considering the sodium salt NaA in water, we have the equation
NaA → Na+ + A-
hence, [A-] = 0.0100 M
Since HA is a weak acid, then A- must be the conjugate base and we can set up an ICE table for the reaction
A- + H2O ⇌ HA + OH-
Initial 0.0100 0 0
Change -x +x +x
Equilibrium 0.0100-x x x
We can now calculate the Kb for A-:
Kb = [HA][OH-] / [A-]
= x<span>²</span> / 0.0100-x
Approximating that x is negligible compared to 0.0100 simplifies the equation to
Kb = (10^-3)² / 0.0100 = 0.000100 = 1.00x10^-4
We can finally calculate the Ka for HA from the Kb, since we know that Kw = Ka*Kb = 1.0 x 10^-14:
Ka = Kw / Kb
= 1.00x10^-14 / 1.00x10^-4
= 1.00x10^-10
