Answer:
Zn, Cu, Fe, Mn, Co, Mo
Explanation:
Biogenic elements are chemical elements constantly present in organisms and having definite biological significance(Bowen, 1966).
There are many of these biogenic elements in nature. Among the elements of the d-block, Zn, Cu, Fe, Mn, Co, Mo are worthy of mention among others.
Free ions of d- block metals are not found in the body. The elements are present in the form of bioinorganic complexes of the respective metals. They commonly exist as co-factors of proteins that carry out essential biological functions.
Endothermic reaction is the reaction in which the system absorbs energy. The system absorbs heat and cools the surroundings. Reactants are the substances that are involved in the reaction and at the end of the reaction product are formed.
In the endothermic reaction because heat is absorbed , the products have a higher heat.
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Part (a) :
H₂(g) + I₂(s) → 2 HI(g)
From given table:
G HI = + 1.3 kJ/mol
G H₂ = 0
G I₂ = 0
ΔG = G(products) - G(reactants) = 2 (1.3) = 2.6 kJ/mol
Part (b):
MnO₂(s) + 2 CO(g) → Mn(s) + 2 CO₂(g)
G MnO₂ = - 465.2
G CO = -137.16
G CO₂ = - 394.39
G Mn = 0
ΔG = G(products) - G(reactants) = (1(0) + 2*-394.39) - (-465.2 + 2*-137.16) = - 49.3 kJ/mol
Part (c):
NH₄Cl(s) → NH₃(g) + HCl(g)
ΔG = ΔH - T ΔS
ΔG = (H(products) - H(reactants)) - 298 * (S(products) - S(reactants))
= (-92.31 - 45.94) - (-314.4) - (298 k) * (192.3 + 186.8 - 94.6) J/K
= 176.15 kJ - 84.78 kJ = 91.38 kJ
Answer:
The empirical formula is CH2O, and the molecular formula is some multiple of this
Explanation:
In 100 g of the unknown, there are 40.0⋅g12.011⋅g⋅mol−1 C; 6.7⋅g1.00794⋅g⋅mol−1 H; and 53.5⋅g16.00⋅g⋅mol−1 O.
We divide thru to get, C:H:O = 3.33:6.65:3.34. When we divide each elemental ratio by the LOWEST number, we get an empirical formula of CH2O, i.e. near enough to WHOLE numbers. Now the molecular formula is always a multiple of the empirical formula; i.e. (EF)n=MF.So 60.0⋅g⋅mol−1=n×(12.011+2×1.00794+16.00)g⋅mol−1.Clearly n=2, and the molecular formula is 2×(CH2O) = CxHyOz.