Answer:
1.39
Explanation:
[Hg2Cl2]= 1M
[H^+] = ????
E°cell= 0.35V
E= 0.268 V
Therefore E for the reaction must -0.082 V
n= 2 moles of electrons
From Nernst Equation:
E= E°cell- 0.0592/n log [Red]/[Ox]
0.0268= 0.35- 0.0592/2 log 1/[Ox]^2
-0.082= -0.0296 log 1/[Ox]^2
log 1/[Ox]^2= 0.082/0.0296
log 1/[Ox]^2= 2.77
1/[Ox]^2=Antilog (2.77)
[Ox]^2=1.698×10^-3
[Ox] = 0.0412 M
But pH= -log [H^+]= -log(0.0412)= 1.385
Answer:
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It is soluble in water and slightly soluble in ethanol.
The structure of the alkyl bromides used in a malonic ester synthesis of ethyl 2-methyl-4-pentenoate.
Ethyl 2-methyl-4-pentenoate by Malonic ester synthesis.
The alkylation of diethyl malonate or a related ester of malonic acid at the carbon alpha (immediately next) to both carbonyl groups, followed by conversion to a substituted acetic acid, characterizes the chemical reaction known as the malonic ester synthesis.
As a result, it is evident from the structure of ethyl 2-methyl-4-pentenoate that ethyl and methyl bromides are the alkyl bromides employed.
To learn more about Malonic ester synthesis refer here:
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So we look equation for the free Gibbs free energy (ΔG) which depends on entalpy (ΔH), temperature (T) and entropy (ΔS):
ΔG = ΔH - TΔS
ΔG is negative (-) because the water absorption on the silica gel surface is a spontaneous process.
ΔH is negative (-) because the water absorption on the silica gel surface is a exothermic process (it releases heat and if you want to desorb the water form the silica gen you need to add heat which is a endothermic process).
ΔS is negative (-) because the water is adsorbed, so from disorderly state you take the water molecules and put them in a orderly state and by doing that you decrease the entropy.
