Answer:
When ΔS > ΔH/ T, then the reaction will proceed forward
Explanation:
- The entity that determines the whether a reaction will occur on its own in the forward direction (Spontaneity or Feasibility) is Gibb's free energy.
- Gibb's free energy is the energy available to do work. It is denoted as 'G'. It cannot be easily measured. The change (ΔG) can only be measured. ΔG = ΔH - TΔS
when ΔG is positive, The reaction is not spontaneous (reaction will not occur on its own)
When ΔG is negative, The reaction is spontaneous (reaction will occur on its own)
When ΔG is zero, the reaction is in equilibrium
Option A and E are not correct. ΔH (Enthalpy) cannot determine spontaneity
Option C and D cannot alone determine spontaneity of reaction
For reaction to be spontaneous, TΔS > ΔH
Therefore, ΔS > ΔH/T
Empirical formula is the simplest ratio of whole numbers of components in a compound.
Assuming for 100 g of the compound
Cu As S
mass 48.41 g 19.02 g 32.57 g
number of moles 48.41 / 63.5 g/mol 19.02 / 75 g/mol 32.57 / 32 g/mol
= 0.762 mol = 0.2536 mol = 1.018 mol
divide by the least number of moles
0.762 / 0.2536 0.2536 / 0.2536 1.018 / 0.2536
= 3.00 = 1.00 = 4.01
once they are rounded off
Cu - 3
As - 1
S - 4
therefore empirical formula is Cu₃AsS₄
Answer:
- 13.56 g of sodium chloride are theoretically yielded.
- Limiting reactant is copper (II) chloride and excess reactant is sodium nitrate.
- 0.50 g of sodium nitrate remain when the reaction stops.
- 92.9 % is the percent yield.
Explanation:
Hello!
In this case, according to the question, it is possible to set up the following chemical reaction:
Thus, we can first identify the limiting reactant by computing the yielded mass of sodium chloride, NaCl, by each reactant via stoichiometry:
Thus, we infer that copper (II) chloride is the limiting reactant as it yields the fewest grams of sodium chloride product. Moreover the formed grams of this product are 13.56 g. Then, we take 13.56 g of sodium chloride to compute the consumed mass sodium nitrate as it is in excess:
Therefore, the leftover of sodium nitrate is:
Finally, the percent yield is computed via:
Best regards!
The boxed diagram name is known as the Periodic Table of Elements in which elements are periodically organized by their atomic number.
Answer:
(a). second order.
(b). zeroth order.
(c). one and a half order.
(d). third order.
Explanation:
Hello,
In this case, you just have to add the concentration's powers in each rate law:
(a)
Just the 2-power is present, so it is a second order law.
(b)
No power is present, so it is a zeroth order law.
(c)
1 plus 1/2 gives 1.5, that is why it is a 1.5 (one and a half) order law.
(d)
2 plus 1 gives 3, that is why it is a third order law.
Best regards.