Answer:
a) ΔHvap=35.3395 kJ/mol
b) Tb=98.62 °C
Explanation:
Given the reaction:
C₇H₁₆ (l) ⇔ C₇H₁₆ (g)
Kp=P(C₇H₁₆) since the concentration ratio for a pure liquid is equal to 1.
When
T₁=50°C=323.15K ⇒P₁=0.179
T₂=86°C=359.15K ⇒P₂=0.669
The Clasius-Clapeyron equation is:
ΔHvap=35339.5 J/mol=35.3395 KJ/mol
Normal boiling point ⇒ P=1 atm
Hence, we find the normal boiling point where:
T₁=323.15K
P₁=0.179 atm
P₂=1 atm
T₂=371.77 K= 98.62 °C
Answer:
Option d. 0.10 m Cr₂(SO₄)₃
Explanation:
Formula for the osmotic pressure is determined as:
π = M . R . T . i
So you have to take account the i (Van't Hoff factor, numbers of ions dissolved)
Urea is an organic compound, so the i value is 1
Zync acetate can be dissociated:
Zn(CH₃COO)₂ → 1Zn²⁺ + 2CH₃COO⁻
In this case, the i is 3. (you see, the stoichiometry of ions)
Cr₂(SO₄)₃ → 0.10 m
Chromium sulfate is dissociated:
Cr₂(SO₄)₃ → 2Cr³⁺ + 3SO₄⁻²
i = 5
BaI₂ → 0.16 m
BaI₂ → 1Ba²⁺ + 2I⁻
i = 3
Answer:
37.5 L
Explanation:
Initial Volume, V1 = 15L
Initial Pressure P1 = 4.5 atm
Final Pressure, P2 = 1.8 atm
Final Volume V2 = ?
The relationship between these variables is given as;
P1V1 = P2V2
V2 = PIV1 / P1
Inserting the values;
V2 = 4.5 * 15 / 1.8
V2 = 37.5 L